Voltage readings will vary and are greatly affected and dependent on whether the battery is being charged, discharged or in storage (rest or “open cell” voltage). There are two terms for voltage readings:

2. Open cell voltage.

Charge Voltage: When a battery is charged the plates will polarize and develop a resistance to the charge (surface charge). This resistance will add to the battery voltage and therefore using this voltage reading will not reflect the true state of charge. All the so-called “surface charge” will be removed when the battery is being discharged. In general, the battery voltage will recover or increase when the load is removed. This is especially true if the load is very high.

Open Cell Voltage is determined by taking all the loads off of the battery and letting the battery stand for at least 4 hours before taking a reading. This allows the surface charge to dissipate. To get around this problem either use table 2 or determine the 50% state of charge as described.

Determining the 50% state of charge Voltage Reading

Most three steps chargers or inverters monitor the voltage and have an adjustable set point that determines when the batteries are low (50% discharged) and should be charged. Once this set-point is reached the inverter will either sound an alarm or start a generator or tie the battery bank back into to grid power. The voltage set-point maybe factory set but could require verification. Consult your inverter manual for the section on “Cut-off voltage” or “Over discharge protection”. Since the voltage will change depending on whether or not the bank is on load the set point can be determined by a specific gravity reading. A gravity reading of 1.200 is equal to 50% discharged.

Battery cable lengths, system set-up and other variables can affect the voltage readings as well. Below is a procedure to verify the 50% mark and table 2 gives approximate cut-off voltages at various state of charge. Notice 100% is given as an open cell voltage and all other as under load.

When using a generator with a low voltage cut-off, set the generator to start at the 50% mark given by table 2 and put the bank into service (11.6 V for a 12V system). When the generator starts-up measure the specific gravity of one cell in the bank. Compare this to the table 1, Specific gravity versus state of charge. If the measured specific gravity indicates the state of charge is more than 50%, decrease the low voltage cut-off setting. Similarly if the specific gravity indicates the state of charge is lower than 50%, increase the low voltage cut-off setting. Note: 50% is the desired depth of discharge but it does not have to be exactly 50%. For practical purposes a range of 45-55% is acceptable. The actual battery voltage corresponding to 50% will change with a change in load. In general, the higher the discharge amperage, the lower the corresponding voltage.

To determine or verify the 50% voltage set point:

1. Put all or as many loads as possible on the battery. Disconnect any in coming current inputs such as panels / windmills and grid power. Contact your dealer for specifics.
2. Take the specific gravity of one cell.
3. Take another reading 15 minutes and ½ hr later this should give you an indication of how fast the batteries are dropping.
4. Continue to take readings until 50-55% state of charge is reached according to the specific gravity readings.
5. Take and record voltage readings (when on load) of any meters to be used for monitoring the state of charge and take a voltage reading across the terminals of one battery.
6. Compare to table 2.
7. These readings will then give you a very accurate voltage reading which can be used in the future either as a set point for the inverter or as a day to day monitoring parameter.

Table 2.

 % Charged Single Cell 12V 24V 32V 48V 100% 2.10 12.60 25.20 33.60 50.40 OPEN CELL 75% 2.01 12.06 24.12 32.16 48.24 UNDER LOAD 50% 1.93 11.58 23.16 30.88 46.32 UNDER LOAD 25% 1.84 11.04 22.08 29.44 44.16 UNDER LOAD 0% 1.75 10.50 21.00 28.00 42.00 UNDER LOAD

Note: This will provide a good indication how your battery bank will behave and how long it will last with no power inputs. It is expected that new deep cycle lead-acid batteries will have an approximate initial capacity of ~75-80% of their rated capacity when first installed. Capacity will increase as the plates continue to form through repeated charge/discharge, reaching the full rated capacity when the battery has been cycled ~60-80 times.